Liverpool vs PSV Prediction and Betting Tips for the UEFA Champions League showdown, scheduled for Wednesday, November 26, 2025, at 20:00 GMT. The game will be broadcast live on TNT Sports 2 and Discovery+, from the legendary Anfield Stadium in Liverpool. In this preview, we’ll break down form, stats, and tactics while giving our take on the best picks from our Champions League Predictions series at XpertStats.

• Arne Slot faces his toughest European challenge yet as Liverpool host PSV at Anfield.
• Liverpool have won 13 consecutive home matches in the Champions League group stage.
• PSV are unbeaten in their last 11 matches across all competitions.
• Ricardo Pepi and Guus Til are in top form for the visitors, while Salah chases history.

It’s been a turbulent few weeks for Liverpool. Their 3-0 defeat to Nottingham Forest on Saturday added to a nightmare domestic run that’s seen them lose six of their last seven in the Premier League. Arne Slot’s men look disjointed, lacking confidence and structure. Still, Europe’s been kinder. Three wins from four have steadied the ship, including a crucial 1-0 triumph over Real Madrid. Yet, Slot’s track record against PSV is worrying, just one win in eight tries. Can he finally shake off that hoodoo under the Anfield lights?

The good news for the Reds? Anfield remains a fortress in Europe. Liverpool have won their last 13 Champions League group-phase games at home, the longest such streak by an English club. Only one defeat in their past 25 home European fixtures says it all. Players like Dominik Szoboszlai and Cody Gakpo have been among the top creators in this campaign, and the attacking stats back it up, Liverpool sit among the top three for direct attacks, proving they can still slice through defenses when it clicks. That said, the pressure’s mounting. One more domestic stumble could spill into their European form.

For PSV, this feels like a golden opportunity. Peter Bosz’s side arrive unbeaten in 11, riding a wave of confidence after dismantling NAC Breda at the weekend. Their Champions League form tells a story of grit, one win, two draws, and just one defeat, but their nine goals scored underline their fearless approach. With Ricardo Pepi involved in five goals in his last four European games, and Guus Til in blistering domestic form, the Dutch champions are bringing real firepower to Merseyside. History may not favor them (just one win in their last 14 away games vs English clubs), but this Liverpool side looks fragile.

Expect chaos, goals, and late drama. PSV have scored more goals after the 86th minute than any team in this year’s competition. Liverpool, meanwhile, can’t seem to keep a clean sheet, conceding three in consecutive league matches for the first time since 1965. So, yes, all signs point to a thriller. Whether Slot’s Reds can finally turn the tide or PSV deepen their misery, one thing’s certain, this could be one of Anfield’s most unpredictable European nights. For those following our Champions League Predictions, brace for goals and plenty of edge-of-your-seat action.